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When water was the reaction medium, the reaction time was not over 6 h, according to the XRD analysis, the product was impure.
Using chemometric methods (Factorial Design and Response Surface Methodology), it was possible to evaluate the role of interaction between pH of the reaction medium, the reaction time and concentration of TiO2, optimizing the conditions for degradation using artificial radiation.
Contrary to studies made in diluted medium, the reaction we describe leads to a strongly grafted polymer on the surface at pH values superior to 6, and up to 13, in an irreversible way.
Linoleic acid was completely epoxidized when used at a concentration of 0.5-2 M in toluene at 30°C, while in a solvent-free medium, the reaction was not complete due to the formation of a solid or a highly viscous oily phase, creating mass transfer limitations.
In the special case, where iodo acetate was added to the medium, the reaction representing glyceraldehyde 3-phosphate dehydrogenase was removed and the reactions in the glyoxylate cycle were included (Supplementary Table S3).
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In acidic medium, the reactions were characterized by an induction period while no such period was observed in alkaline medium.
In an acidic medium, the reactions were characterized by two stages: formation of the passive interphase and electropolymerization of the N-methylpyrrole.
ODE is used as a reaction medium, and the reaction temperature is 30 120 °C.
Ionic template was previously dissolved in water with stirring at room temperature, and NH4OH was added to provide the alkaline medium of the reaction.
A pH adjustment was necessary especially given the acidic medium, because the reaction was affected by change in pH over the range 2.5 5.6.
This gas-filled detector uses an active-target design where the gas acts as both the tracking medium and the reaction target.
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