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A new medium intensity band near 3400 3500 cm-1 is attributed to the νOH stretching vibration of the coordinated water molecule to the central metal ion [29].
The peaks appearing at 1,059 cm−1 and 1,097 cm−1 can be attributed due to the asymmetric stretching mode vibration in PO4−3, and a medium intensity band at about 962 cm−1 results from P-O asymmetric stretching of the stretching vibrations in PO4−3[33].
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In addition, the presence of conjugated carbon carbon bond is indicated by the presence of a medium-intensity band at 1262 cm−1.
The Raman spectra of these inclusions exhibit characteristic bands of the cubic form of lead tin yellow (lead tin yellow type II, Pb2Sn1−xSixO3) [18] 18], with a very strong band at 138 cm−1, weak broad bands at 334 and 447 cm−1, and a medium-intensity band at 69 cm−1 (Fig. 4l).
The characteristic C=N band (1680 1520 cm−1) of medium intensity and a medium-strong band at 1300 1050 cm−1 were identified in each IR spectra; the latter could be attributed to the C O C vibration or heteroatom ring deformation of the oxadiazole ring.
A band of medium intensity centred at ~472 cm−1 is assigned to the Si O bending modes of the glaze [13].
Similarly to the 2KWBPU systems made with PUDs (NCP topcoats), the FPU samples produce a single band of medium intensity at around 1690 cm−1, corresponding to the dominant peak observed for HDI cyclic trimers.
The analysis of IR spectral data obtained for compounds 6a j showed that the NH group corresponding to the amide bond formed was identified between 3305 and 3294 cm−1 in the form of a medium or low intensity bands.
Two absorption bands of medium intensity in the region 2850 2940 cm−1 are characteristic of symmetric and asymmetric stretching vibrations of C-H bonds.
The FTIR spectra of PEGDA, EGDMA and PETRA had typical absorption bands of medium intensity at about 1640 cm−1 corresponding to alkenes.
Only in polar protic solvents, intensity of the PT band increases significantly whereas in non-polar or polar aprotic medium intensity is sparse.
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