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Os-PVP complex mediated the electron transfer between the electrode surface and CdS NPs.
The results indicated that the phenylazo low-lying π-orbital participated in the hopping mechanism that mediated the electron transfer in the LB films with few molecular layers.
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Importantly, besides utilizing nanowires to mediate the electron transport [165], they can synthesize their own redox mediators (i.e. flavins) for extracellular electron transfer under diverse environmental conditions [163, 166].
As known, Au can accept electrons and mediate the electron transfer process with functional groups thereby generating charge separation and drastic re-arrangement of surface electrons [16, 17].
It was also found that C60 L is capable of mediating the electron transfer to chloroacetic acid, promoting its electrocatalytic reduction.
It is therefore likely that Fe(II)/Fe(III) serves as an electron shuttle, mediating the electron transfer between Cr VI) and sulfide as illustrated below: (4).
And H+ ions as the electron donors at pH6 can mediate the electron transfer between Fe2+ and X2+ to modify the Fe3O4 surface.
The reduced Fe2+ ion plays an important role in compensating for the charge imbalance and also mediates the electron transfer between MR-1 and X2+.
The primary role of MA in the ZVI/O2 system seems to mediate the electron transfer from the ZVI surface to dioxygen.
PHQ retains its redox activity and reversibility in the solid state and effectively mediates the electron transfer between the electrode and GOD.
It was found that C60-L/Nafion is capable of mediating the electron transfer to α-halogenated organic acid, showing it could be used to catalytically reduce the above organohalide compounds, except for 4-bromobutyric acid.
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