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Mediated electron transfer (MET) employs redox mediators to shuttle redox equivalents or allow electron hopping between the enzyme and the electrode and has been widely applied to solve this problem.
Additionally, mediated electron transfer (MET) approaches via soluble redox mediators and redox polymers have been pursued.
Although adsorbed FMN cannot participate in mediated electron transfer (MET -type bioelectrocatalysis, dissociated FMET -typeution works as a mediator for MET-type bioelectrocatalysis of the HCOO− oxidissociatedlanar electrodes.
mediated electron transfer.
These results are rationalized by considering the mediated electron transfer through VASWCNTs.
These systems were designed for the investigations of the kinetics of mediated electron transfer.
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The nature of attractive pairing mechanism with conventional phonon-mediated electron pairing or unconventional electronic mechanisms in superconducting fullerides is, of course, a central point of several experimental studies, which remains unsettled for a quite long time.
It is not surprising that the experimentally measured phonon-mediated electron relaxation turned out to be much faster than it is expected in the phonon bottleneck concept [2].
It is shown that the covalent surface modification is possible because of the intervention of radicals, which are generated in a self-mediated electron transfer process.
Employing saturated concentrations of potassium ferri/ferrocyanide in aqueous solution as electrolyte in combination with the electrodes resulted in a highly feasible redox-mediated electron transfer.
As a result of cyclic voltammetric study, it was shown that peak a originated from the oxidation of reduced viologen moiety via P CPDT -mediated electron transfer mechanism.
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