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Three different initiators were involved to mediate the polymerization of the monomers.
However, NMP suffers from some limitations, in particular to mediate the polymerization of unconjugated monomers or to conduct the polymerization of conjugated monomers under low temperatures.
The PMR-CTA was used to mediate the polymerization of potassium (styrene-4-sulfonyltrifluoromethyl-sulfonyl)imide (STF-K+) and subsequent counter ion exchange resulted in a star-shaped single lithium-ion conducting copolymer (SSCP-Li+).
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The inimer plays the role of both incorporating "T-shaped" inter-chain linkages and mediating the polymerization.
The xanthate-terminated PVDF was then used as the macromolecular chain transfer agent further to mediate the radical polymerization of N-vinylpyrrolidone (NVP) and the PVDF-b-PVPy diblock copolymers were successfully synthesized.
The hydroxyl groups on the silica hollow sphere surface were converted into trithiocarbonate chain transfer agents (CTA), and were further used to mediate the RAFT polymerization of methyl methacrylate (MMA).
Firstly, a novel RAFT agent containing α-alkyne and azobenzene chromophore in R group, 2- 3-ethynylphenylazophenoxycarbonyl prop-2-yl-9H-carbazole-9-carbodithioate (EACDT), was synthesized and used to mediate the RAFT polymerization of styrene (St).
Heme-derivatives can also mediate the oxidative polymerization of DAB.
Further evidence for the pronounced efficacy of this cobalt complex in mediating the radical polymerization of MMA can be found in the good agreement between experimental and theoretical molar masses (Mn,theor/Mn,SEC = 1±0.40, Table 1, for the peak #1).
Indeed, active Rac1, e.g., by triggering integrin activation and actin polymerization, can mediate the R-Ras-elicited and integrin-mediated spreading of ECs on matrix proteins.
RecA polymerization is mediated by the polymerization motif (PM) that is located between the NTD and the CAD.
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