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The effects of laser energy and of external gas pressure on product branching and on the mechanisms of decomposition are discussed.
We highlight the most valuable techniques that we use to asses potential precursors on the basis of the discussed qualities, and to elucidate relevant mechanisms of decomposition and surface reactivity.
There are, however, substantial differences in the reported kinetics and presumed mechanisms of decomposition, which are primarily related to the reactor design thus, reflecting the complexity of chemical reactions involved.
It is notable that for the investigated ligands, there is only one main difference in mechanisms of decomposition: in the next stage after dehydration, in case of methacrylacetophenone complexes, one ligand molecule detaches at temperatures above 260 °C, whereas for allylacetoacetate complexes, the detachment of allyl substituent takes place above 300 °C.
Similar(56)
Thermal analysis reveals the stepwise mechanism of decomposition for CCA.
Mechanism of decomposition of [Pd(C2O4 22− is similar to that of silver oxalate (Ag2C2O4) [22].
Also, the mechanism of decomposition of the latter differed from that of pyrrole, especially on γ-Al2O3.
The number and nature of the intermediates implies that the mechanism of decomposition of lindane is based on both oxidative and reductive processes.
The mechanism of decomposition of N2O on Fe-ZSM-5 prepared by chemical vapor deposition was studied by step and pulse response experiments and by isotope labeling.
Hence, mechanism of decomposition of [Pd(C2O4 22− can be explained as follows. In this reaction, oxalate di anion in the intermediate complex, [Pd(C2O4 22−, absorbs the light in the UV region [24], get excited and decomposes to CO2.
The thermal stability of the cyclizable form of the fluorinated adamantylidene indolylfulgides was greater than that of their corresponding fluorinated isopropylidene analogs, as expected based upon the mechanism of decomposition for isopropylidene analogs.
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