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The degradation mechanisms in solid oxide fuel cells are caused by microstructural changes, reactions between lanthanum strontium manganite and electrolyte, poisoning by chromium, carburization on nickel particles, formation of nickel sulfide, nickel coarsening, nickel oxidation, loss of conductivity and crack formation in the electrolyte.
The specific advantages of this method (low temperature chemical process, large variety of material precursors, material structure adaptability, and coating process possibilities) are described here in relation with transport mechanisms in solid matrices, as a very suitable way to design and synthesize membranes with improved performance.
Because the effects of glutathione on radiation and chemotherapy resistance are likely to be greater under hypoxic conditions, these results have potentially important implications for the study of resistance mechanisms in solid tumours.
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High-pressure X-ray crystallographic studies of atomic structure reveal three principal compression mechanisms in solids: bond compression, bond-angle bending, and intermolecular compression; they are illustrated in Figure 1.
The computational modeling of failure mechanisms in solids due to fracture based on sharp crack discontinuities suffers in situations with complex crack topologies.
For example, it is possible that the general mechanism dominates in solid substrates such as soil whereas the specific mechanisms are more valid in bulk aqueous media.
A full elliptic two-dimensional numerical code that included elementary hetero-/homogeneous chemical reaction schemes and relevant heat transfer mechanisms in the solid was used in the simulations.
At steady operation the catalyst surface temperatures exceeded by 200 K the adiabatic equilibrium temperature and standard (passive) heat transfer mechanisms in the solid were shown to be ineffective in providing proper reactor thermal management.
The mechanism involved in solid phase extraction (SPE) depends on the nature of the sorbent and analyte.
This chapter provides important mathematical bases of diffusion for a variety of experimental situations and diffusion mechanisms in crystalline solids.
The algebraic expression of functions of the most common reaction mechanisms operating in solid-state reactions are presented in some papers [23 25, 27, 29].
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