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Furthermore, we discuss possible interface mechanisms during catalyst layer formation and CNT growth.
Catalysts were characterized by using X-ray diffraction (XRD), 27Al solid state nuclear magnetic resonance (NMR) and transmission electron microscopy (TEM /energy dispersive X-ray (EDX) spectroscopy to develop an understanding of degradation mechanisms during catalyst aging.
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Possible mechanisms of catalyst deactivation and modification of cobalt active sites during the reaction are also discussed.
Comparison between experimental and simulation N2 isotherms during catalyst deactivation shows excellent agreement between model and experiment confirming the mechanism of coke formation.
The literature treating mechanisms of catalyst deactivation is reviewed.
Additionally, aging of precipitates during catalyst synthesis improved stability.
These Fe concentrations in the interior parts of the particle are not deposited during catalyst aging but belong to Fe-rich matrix components of the catalyst particle.
The complexity of polyalcohols, such as ethanol and glycerol that involve many intermediate reaction mechanisms during oxidation, makes it difficult to use lower catalyst loadings.
Special attention is paid to the roles of metal particles and the deactivation mechanism of the catalyst during the reaction.
Understanding the structural and electronic mechanisms by which catalysts activate and deactivate during use is crucial to the intelligent design of more efficient chemical syntheses.
From our work it can be concluded that oxidation is not a deactivation mechanism during FTS for supported Co catalysts with crystallite size in excess of 2 nm.
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