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This development has paved the way for further controlled polymerisations, and, by understanding the reaction mechanism of guest molecules, has allowed for the design of new frameworks for molecular confinement, alignment and conversion.
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To elucidate a mechanism by which the admission of guest molecules can be thermally regulated, this work presents experimental data and ab initio calculations that explain the phenomenon for several types of microporous materials including trapdoor zeolites, supramolecular hosts27,28 and MOFs.
Effects of the calixarene conformation and substituents on the lower and/or upper rims on the mechanism for guest-induced changes in the dansyl-group fluorescence are discussed.
Traditional methods, such as NMR spectroscopy, have served instrumental in studying equilibrium conditions, diffusion of guest molecules, and self-sorting mechanisms of hydrogen-bonded and nonparamagnetic nanoassemblies in solution.
The structure of the CLR01-lysine complex and the precise mechanism of lysine threading into the CLR01 guest cavity and subsequent ion pairing have been extensively characterized by NMR spectroscopy, crystal structure, molecular dynamics, and quantum mechanics/molecular mechanics (QM/MM) calculations (Bier et al., 2013; Dutt et al., 2013; Klärner and Schrader, 2013).
The mechanism of the controlled binding and release of guests in hemicarcerands was elucidated through computational studies by Nakamura in our group in the 1990s.
The intensities of the bands sensitive to the amount of guest molecules and the conformational order of sPS were followed to clarify the mechanism on the guest exchange.
The transition temperature decreases with increasing concentration of guest PEG.
Out of guest module: It resides in a secure VM.
CDs form host guest inclusion complexes upon penetration of guest molecule in the central cavity of host CDs.
The excited guest molecules could interact with the ground states of guest molecules (M 2) and induced excimer emission.
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