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The former is limited by high dielectric loss resulting from the interface; the latter offers mechanical flexibility with facile processing.
QJ Huang reported AZO/AgNWs/AZO deposited onto polyimide films, which displays excellent thermostability and mechanical flexibility with the low surface roughness (R-rms < 8 nm).
Furthermore, the fibriform supercapacitor shows substantial mechanical flexibility with minor capacitance decrease upon continuous bending cycles, and the knitted fibriform supercapacitor exhibits the excellent wearability and integration.
The composite also demonstrates excellent long-term cycling stability with 34% capacitance increase after 10,000 cycles and mechanical flexibility with 40% capacitance increase after 4000 bending cycles.
In addition, these supercapacitors exhibited high rate performance with capacitance retention of 85% by increasing the current density from 1.0 to 20.0 A g−1, and excellent mechanical flexibility with only 4.9% decay in the performance when bent 180°.
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These fabricated hybrid structures present superb mechanical flexibility (folding with bending radius of approximately 3.7 μm) and stretchability (10,000 times in a fatigue test with maximum stretching strain of 100% and stretching in tensile strain of 30% toward multi-axial direction).
Polymer-based structures have several exclusive advantages over other materials: (1) scalability; (2) wide tunability; (3) ease of functionalization; (4) mechanical flexibility; (5) compatibility with various patterning methods; (6) relatively low cost; (7) light-weight.
A functionally graded Al-doped ZnO structure is presented which combines conductivity, visible transparency and light scattering with mechanical flexibility.
However, their technological drawbacks have hindered the development of fully flexible electronics because of a lack of reliable electrode materials that combine superior electrochemical properties with mechanical flexibility.
Conducting polymers offer some advantages, such as light weight, low cost, mechanical flexibility and excellent compatibility with plastic substrates for the development of next-generation display technologies and, in particular, are expected to play an important role in the development of flexible display technologies.
Highly ion-conductive gel polymer electrolyte (GPE) with mechanical flexibility is developed by incorporating liquid electrolyte into polymer films that are fabricated by initiator-free photopolymerization of poly ethylene glycol) dimethacrylate (acrylate monomer) and pentaerythritol tetrakis (3-mercaptopropionate) (thiol monomer) blend.
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