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Kinetic parameters such as frequency factor, energy of activation and reaction orders were determined for the consecutive reactions from hematite to magnetite, magnetite to wuestite and wuestite to iron by numerical integration and parameter estimation from measured rate data.
Consequently, we used 90 mM hydroxylamine, a relatively strong nucleophile at pH 7 (33), to accelerate the hydrolysis of acyl-ACP to thiol-containing holo-ACP and produce a more conveniently measured rate (data not shown).
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The Poisson mixed effects model provides an appropriate mechanism for handling repeated measures rate data while allowing for the inclusion of available data from participants who had missing evaluation time points.
A new gas solid model is formulated to describe the entire experimental carbonation history, with measured rate constant and pore size distribution data as input.
A correlation for the evaporation of sessile drops over a very broad range of conditions was developed based on measured evaporation rate data obtained for drops of acetone, methanol, and six hydrocarbons ranging from hexane to isooctane, evaporating in air, helium, argon, and krypton, over a range of ambient pressures from 96 kPa to 615 kPa.
Measured diopside rate data and solution compositions are from Golubev et al. [35].
Measured diopside rate data and solution compositions are from Golubev et al. [35]; solution speciation and were calculated using Supcrit92 thermodynamic data base where log Keq = 20.96 for diopside solubility [22].
Within the universe of 251 possible EMs, 20 of them captured up to 93% of the measured rates variance, even though the data were pooled together from several independent cultivation experiments, with inherently diverse environmental trajectories.
Both models calibrated with the high temperature data under predict measured rates at 25°C.
The study further indicates the building and measurement data that are critical for a more accurate validation of thermal-ventilation models, including, on-site measured temperature, wind, and solar conditions; measured volume flow rate data, at critical points throughout the building; and effective area and discharge coefficients for specific vents used in building.
A kinetic model was developed to correlate the experimentally measured gas consumption rate data.
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