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Unfiltered PVAc sample showed components with MWs close to 109 g/mol and root mean square radius rrms values approaching 400 nm.
The parameters studied were the mean square radius of gyration, the intrinsic viscosity, and the differential polarizability and extinction angle that are parameters relevant in flow birefringence studies.
This paper describes a kinetic method to predict the z-average molecular mean square radius of gyration of tree-like polymers formed by irreversible reactions, assuming Gaussian chains.
Molecular weight distribution and mean square radius as a function of molecular weight for biodegradable aliphatic polyesters have been measured by multiangle laser light scattering (MALLS) detector for size exclusion chromatography (s.e.c).e.c
The lower diffusion coefficient of the small cyclic alkanes was attributed to the high local density within the volume defined by the smaller mean square radius of gyration of the cyclic alkanes.
This conclusion requires modification if the end effects are defined differently, using the mean square radius of gyration of the n+1 chain atoms about chain atom i, denoted ⟨s2i⟩0.
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The susceptibility χ is given by where Σ < r2 > is the sum of the mean square radii of all electron orbits in each atom, e and m are the charge and mass of the electron, and N is the number of atoms per unit volume.
With the help of the size distribution functions, the k-th mean square radii of gyration of hyperbranched polymers with and without a core are derived, respectively.
Directly solving for persistence length by non-linear regression is more suitable than linear approximations that use ratios of root-mean-square radius and molar mass.
The root mean-square radius of gyration (⟨r2g⟩1/2), intrinsic viscosity, and molecular mass (M) of the PEs were measured for each elution fraction.
These molecular parameters represented the molecular weight dependence of and the mean-square radius of gyration 〈s2〉z, reasonably indicating an effect of the excluded volume at large Mw.
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