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The results show that the calculated mean activity coefficients of the electrolytes studied are in good agreement with experimental values obtained from the literature.
In this article, a revised LIQUAC and LIFAC model is presented, which enables the user to describe mean activity coefficients, osmotic coefficients and also vapor liquid equilibria reliably.
To calculate the mean activity coefficients of the electrolyte portion, a correlation on the basis of existing osmotic coefficient and activity coefficient values is employed.
Mean activity coefficients of NaBr and thermodynamic functions ΔG0t, ΔH0t and ΔS0t for transfer of NaBr from water to 2-propanol water mixtures have also been calculated.
These data were used in calculations of: (a) the mean activity coefficients of zinc chloride (b) the primary medium effect (c) the standard Gibbs energies of transfer of zinc chloride from water to mixed solvents.
In order to perform this analysis the mean activity coefficients of the salt in the presence of DMSO were experimentally determined and the electrical double layer parameters calculated by using Fawcett's function.
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Secondly, to calculate the solution chemical potential more easily, average mean activity coefficient and average osmotic coefficient were used.
This activity coefficient is designated by γ± to indicate that it is a mean activity coefficient for the positive and negative ions.
The mean activity coefficient of HCl, γ±, is determined for molalities between 0.01 and 0.05 m in each case.
The new eEOS is applied for correlation of mean activity coefficient and prediction of osmotic coefficient of various strong aqueous electrolyte solutions at 25 °C and 0.1 MPa.
From the variation of the mean activity coefficient with temperature, the relative partial molal heat content 2 of HCl is computed.
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