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For very fast transients below the steady-state time constant, the on-rate for the indicator may not be fast enough and also binding of calcium to the indicator may be diffusion limited.
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The apparent stability of the spherical diffusion model with regard to time dependency of its parameters indicates that sorptive uptake may be diffusion-controlled.
The second-order rate constant for association suggests that the process may be diffusion-controlled (13).
The association rate constants are similar and may be diffusion-controlled.
Kinetic measurements showed rapid binding of SSB to ssDNA, and this may be diffusion-controlled (13): this work also examined different lengths and different salt conditions.
The maintenance of PvO2 when perfusion is thought to decline and PtO2 decreases suggests that there may be a diffusion limitation, possibly due to selective perfusion.
The additional components captured by MEMFCS, which are discarded when using polymer models, indicate that there may be additional diffusion coefficients for the same probe within these crowded mixtures.
Therefore, it means that the rate of attainment to equilibrium may be particle-diffusion controlled (Yang and Al-Duri 2005).
The rate-limiting step in the adsorption may be either film diffusion or intraparticle diffusion.
The rate of the growth may be controlled by diffusion in solution (n ≈ 1), diffusion at the particle surface (n ≈ 2), or the interface dissolution/precipitation step (n ≈ 3).
The Stefan Maxwell approach provides a general theoretical framework so that measured or predicted binary diffusion coefficients may be utilized for multicomponent diffusion (for which Fick's law is invalid).
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