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Mass spectrometry operating conditions were optimised in order to achieve maximum sensitivity values: negative and positive ionization mode, scan spectra from m/z 100 to 1500, was used with a gas temperature of 350°C, nitrogen flow rate of 10 l/min, nebulizer pressure 30 psi, quadrupole temperature 30°C, capillary voltage 3500 V.
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Simple tuning rules are generated by considering specific values for the maximum sensitivity value.
The maximum sensitivity value is one of the largest reported so far for luminescent ratiometric thermometers.
Among the different ways of introducing a robustness constraint into the design stage, the purpose of this paper is to use the maximum sensitivity value as the design parameter.
Plot of the maximum sensitivity value for each peak as a function of C2H2 concentration (d).
Maximum sensitivity value for each peak as a function of H2 concentration (d).
Although pure CNTs are able to detect C2H2, with a maximum sensitivity of 0.37% for Au-CNT(A and B), the maximum sensitivity value was close 0.90%.
Moreover, we defined a scaling factor in Table 1 as the copy number that provides the maximum sensitivity value.
Because the sensitivity value changes depending on copy number variation, we obtained a maximum sensitivity value by changing the copy number variation from 0.001 to 1000.
For the optimized sensors, maximum mass sensitivity values were as high as 4.309 μm2/pg for device A operating at 0.7477 GHz, and 8.643 μm2/pg for device B operating at 1.5860 GHz.
Regarding the performance of the sample, the maximum GMI sensitivity values achieved in case of longitunal anisotropy are 6%/Oe from the single peak to the saturation field at 500 MHz (quasistatic regime), and 12%/Oe from the FMR peaks to zero-field at 1.12 GHz (dynamic regime).
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