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The maximum phenol uptake under these experimental conditions was 98.31%.
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However, other reasons could be related to the kinetics of the phenol uptake, which could have reached its maximum value, or to a complex of different stoichiometries formed at the highest phenol concentration less soluble in the PIM core.
However, the results also indicated that up to 50%% of the total amount of phenol uptake was found to occur in the first 30 min, and thereafter, the rest 50%% of maximum uptake was reached in 24 h.
Maximum phenol conversion was of 35.1%.
Data confirmed that the total amount of sorbed phenol and equilibrium phenol uptake decreased with increasing flow rate and increased with increasing inlet phenol concentration.
It is also seen that an increase in Co resulted in increased phenol uptake.
Further, increase in pH causes again increase in phenol uptake showing the neutralization acidic surface groups present onto TCAC.
Highlighted lines: the isoline Φ = 1 in red, the maximum phenol conversion in green.
The maximum phenol adsorption capacity onto OPA is found to be 3.55 mgg−1 at 303 K.
They are some literature references concerning the phenol adsorption on organobentonite (Juang et al. 2002; Vianna et al. 2004), but in our opinion they need further verification, especially in respect to the pH influence on the phenol uptake by adsorbent.
The influence of different experimental parameters (initial concentration, pH, adsorbents dose, contact time, stirring rate and temperature) on phenol uptake efficiency was evaluated.
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