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From the experimental results the maximum methanol conversion, hydrogen yield, and CO conversion achieved were 97%, 2.38, and 70%, respectively.
Among these three configurations, the flow through catalytic membrane reactor demonstrates the maximum methanol conversion of 36.4% and 100% selectivity toward DME.
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In comparison with a traditional reformer, the reformer with a diffuser of θd = 6° and Ld = 75 mm obtains the maximum enhancement of 22.96% in methanol conversion, 44.62% in hydrogen production, and 24.59% in estimated net power of fuel cell at wall temperature of 250 °C.
The simulations reveal that a maximum in the hydrogen productivity occurs at an intermediate value of the space velocity, implying a trade-off between reactor size, methanol conversion and hydrogen utilization.
Methanol conversion {text{Conversion}}_{text{methanol}} = frac{{{text{methanol}}_{text{in}} - {text{methanol}}_{text{out}} }}{{{text{methanol}}_{text{in}} }} times 100, {text{wt}}%.
Methanol conversion takes place at 493 K.
Methanol conversion was nearly complete and the self-decomposition of methanol can be suppressed significantly.
Correction factor for methanol, methanol conversion, and product yield were calculated as follows: Correction factor for methanol {text{F}}_{text{methanol}} = frac{{m_{text{methanol}} times S_{text{ethanol}} }}{{S_{text{methanol}} times m_{text{ethanol}} }}.
The methanol conversion was determined by the amount of methanol remaining in the liquid product (both oil and water phases).
Methanol is a similar 'platform chemical,' and most methanol conversion reactions proceed via DME as an intermediate.
The results indicate that the diffuser obviously enhances methanol conversion and hydrogen production of a cylindrical methanol steam reformer.
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