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The concentration range for maximum gel fraction also shifted to higher solute concentrations.
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Figure 2b represents the gel fraction of TMSC-films containing 2 wt% NHNA and 5 wt% NHNA as a function of the irradiation dose, revealing maximum gel fractions of 73 and 98%%, respectively, after UV-illumination with an irradiation dose of E ≥0.97 J cm−2.
Moreover, the critical solute concentration required for gelation and the maximum of the gel fraction shifted towards higher concentrations.
The gel fraction showed a plateau type maximum in a wide solute concentration range, but decreased with high slope under and over the critical concentration values.
At the concentrations tested, maximum gel elasticity values were obtained when the soluble alginate fraction was kept at about 30% of the total alginate content.
After this, the gel fraction increased quickly.
For pure CMC gels the highest gel fraction was observed in the 15 30 w/w% range at 20 kGy.
However, between 10 and 50% starch content the gel fraction did not change and at 10 kGy above 50% a sudden decrease was observed in the gel fraction.
Lowering the dose to 10 kGy resulted in lower gel fraction but higher water uptake.
The gel fraction contents associated with CER samples were determined after ethanol extraction.
At higher doses the gelation improved significantly and 35 40% gel fraction was reached.
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