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Pyrolytic carbon layers were deposited from methane/oxygen/argon mixtures on planar substrates (silicon wafers) at a total pressure of 100 kPa, a maximum gas residence time of 2 s and a temperature of 1100 °C.
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This interaction between bubble diameter, gas residence time and maximum concentration of intermediate is resolved by recourse to a three dimensional diagram which optimises the production of intermediate for any given value of bubble diameter or gas residence time.
For the zero first order reaction sequence, the gas residence time at which the maximum concentration of R occurs is shown to be fixed and independent of bubble size in the bed.
On the other hand, for a first first order reaction scheme, an optimum gas residence time exists for the concentration maximum to occur at the bed exit.
The thickness profile as a function of the gas residence time in the discharge clearly shows two maxima.
The gas yield increases with increasing gas residence time when temperature of the residence zone is higher than 700 °C.
However, since gas residence time is short in engineering applications, the influence of gas residence time is quite moderate.
The optimum conditions at applied voltage 7.3 kV @ 50 Hz were: 10,400 ppm water vapor concentration, 12 s gas residence time, in a single pyrex dielectric barrier reactor with 2 mm gas-gap and 13.5 mL gas volume capacity, yielding the maximum hydrogen concentration of 1500 ppm.
Mean gas residence time for experiment 6 (B) and for experiment 7 (C) is shown.
Mean gas residence time was evaluated by linear interpolation between the measurement points.
Entrained flow gasifiers are high capacity gasifiers because the gas residence time is measured in seconds.
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