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The maximum decolorization rate was observed for US compared to UV and combination of US UV.
The double reciprocal plot for kinetics yield maximum decolorization rate, Vm = 120.48 h−1 and half saturation constant, Km = 1674 mg/L.
Various process parameters such as enzyme concentration (10 U/ml), dye concentration (10 mg/l), temperature (25 °C) and reaction time (150 min) were successfully optimized to achieve maximum decolorization rate.
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Decolorization rate was maximum for US UV followed by US and UV, respectively.
As a result, the maximum enhancement of the volumetric decolorization rate (vDR) can reach to 255%, even when the c-SMEM and p-SMEM have the same electrode surface area.
Bacterial culture generally exhibits maximum decolorization at pH 5 (59.6%) whereas the rate of color removal tends to decrease rapidly at highly acidic or alkaline pH.
The maximum decolorization, TOC removal, and pseudo-first-order degradation rate constant were 94.8, 38.8, and 30.8 min−1, respectively.
Optimization results showed that maximum decolorization efficiency was achieved at the optimum conditions: initial dye concentration 10 mg/L, UV light intensity 47.2 W/m2, flow rate 100 mL/min and reaction time 120 min.
Optimization results showed that maximum decolorization efficiency was achieved at the optimum conditions: initial dye concentration 10 mg/L, UV light intensity 47.2 W/m2, flow rate 100 mL/min and reaction time 200 min.
Decolorization rate was also found to increase with the increase in catalyst (iron-containing waste) concentration till reaching maximum value and then slightly decreased upon further addition of the catalyst (Fig. 6).
Therefore, the decolorization rate also reduces.
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