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The maximum conversion and ≥99% enantiomeric excess were obtained in less than 2 hours for the synthesis of (R -mandelonitrile and (2 S)-fuR -mandelonitrilecetonitrile (Tande 1, entries 1 and 5).
Typical cells with maximum conversion and durability revealed η and D in the range of (7.17 7.28) and (1700 2000 h), respectively.
The results obtained suggest that the properties required for a best-performing catalyst (maximum conversion and lowest deactivation rate) are different for these two alkenes.
Two different types of optimisation problems, namely, maximum conversion and minimum time problems are formulated and solved and optimal operation policies in terms of reactor temperature or coolant flow rate are obtained.
Process feasibility as well as membrane resistance is tested; maximum conversion and process rate are greatly affected by the ratio between protons in the acid solution and sodium ions in the process salt solution.
The maximum conversion and yield in the reactor were 85%and63%3%, respectively, using a reaction-separation zone of 30% Lmem/Lmax at molar ratio methanol to oil of 9 1.
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And for different operating temperatures, the maximum conversion efficiency and maximum stress level of TE materials are also investigated, individually.
Doses of pre-cooking α-amylase, post-cooking α-amylase, glucoamylase and saccharification temperature were found to produce maximum conversion efficiency and were these selected for optimization.
The maximum conversion rate and quantum efficiency in the model are 0.235 μmol g−1h−1 and 0.0177% respectively, both higher than previous internally illuminated monolith reactor (0.16 μmol g−1h−1 and 0.012%).
Table 3 shows maximum conversion (80.4 and 85.7 %) with the higher selectivity towards triacetin formation (30.1 and 43.2 %) at increase amount of mole ratio such as 1 20 and 1 25.
The OBR demonstrated a 94 99% decrease in the required power density to achieve maximum conversion rates and showed a 12% increase in glucose production after 24 h at 2.36 W/m3.
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