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The effective charge transfer was found to be around 0.47 e per single TCNQ molecule when graphene sheet was sandwiched by two TCNQ molecules with the lowest adsorption energy, although maximum charge transfer amount was only 0.29 e in the case of adsorption on one side.
It was also reported that the affinity of the protonated DETA-PES membrane to phosphate was stronger than that to Cl– and, due to the maximum charge transfer between phosphate and the (DETA-PES-H n )+ chain, and the more negative adsorption energy and Gibbs free energy of adsorption for the formed (DETA-PES-H n )+ H2PO4 complex.
Optimal parameters ensuring minimum irreversible capacity of the substrate were defined: medium binding of Li combined with maximum charge transfer – requirements met by BN-anthracenes and B-phenanthrenes at low degree of doping and B-anthracenes with higher B-contents, the two latter being more prospective.
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The DMFC test results indicate that the MEA prepared from Pd3Co/C cathode exhibits better performance compared to the MEA prepared from Pt/C (Electrochem) and an in-house Pd/C catalyst synthesized, in terms of maximum power density and minimum charge transfer resistance.
Impedance tests have shown maxima in the charge transfer resistance vs cycle number for these two cathodes, this being reflected in the capacity trends during cycling.
The charge transfer resistance was maximum among R s, R ct and R d in MFC-1 (Table 3), whereas in MFC-2 and MFC-4 using NDCP, diffusion resistance was the limiting resistance.
Ross-Medgaarden and Wachs [14] also reported the Eg value of wolframite NiWO4 as ~4.5 eV, which is higher than this finding with ligand-to-metal charge transfer (LCMT) band maximum between 247-252 and 342-344 nm, due to the distortion nature in isolated WO6 units.
Closely related AoCld, DaCld and IdCld (Table 1) exhibit a relatively broad Soret maximum at around 393 nm and charge transfer bands at around 510 and 645 nm with a Qv band at approximately 535 nm at neutral pH.
Using EIS, the maximum phase angle (Φmax) and the interfacial charge transfer resistance (Rct) increased significantly using 100 μg and 1000 μg of TiO2 and ZnO respectively.
The sample with highest value of PEG showed the maximum specific capacitance (68.5 mF cm−2) and the smallest charge transfer resistance (565 Ω) among all samples.
Accordingly, we attribute the broad, intense band with a maximum at 246 nm in the excitation spectrum to the charge transfer state from the silica framework oxygen ions to europium ions.
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