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A maximum chain orientation parameter of 0.23 was determined for fibers collected between 8.1 and 9.8 m/s.
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In contrast, fibers drawn up to the maximum draw ratio at 140 °C display the single α phase with a high degree of chain orientation.
This excess appears to be strongly anisotropic and is maximum when the light polarization is orthogonal to the principal tensile strain component, i.e. to the chain orientation direction.
We have studied the effect on the Raman spectrum of the polymer chain orientation.
The fibers spun at low humidity contain more β-sheet structure and lower degree of chain orientation and crystalline orientation.
The effect of orientation on the carrier injection and transport properties depending on the chain orientation direction was evidenced.
However, the amorphous chain orientation was much lower.
Chain orientation, coil deformation and relaxation were analyzed.
These polymers exhibited high crystallinity with a predominant edge-on chain orientation on the substrate.
LLH chain orientation (scFv in Vl-linker-Vh chain arrangement) retained strong binding to the antigen [31], therefore the same orientation was chosen for the humanized V5B2 scFvs.
The side chains of neighboring residues, Leu184 and Cys190, help position the side chain orientation of Thr193 through hydrophobic packing with its Cγ atom.
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