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Simplex optimization was used to reach a maximum catalytic peak current for the reduction of oxygen using a modified electrode consisting of carbon paste mixed with the sodium form of zeolite Y.
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We performed a cyclic voltammetric study on solutions of H2O2 ranging from 0 to 2 mM and typical voltammograms obtained at 5 mV s 1 can be seen in Figure 2 A. A plot of the concentration of H2O2 versus peak current yields a logarithmic relationship with a maximum catalytic velocity reached by a concentration of 2 mM H2O2.
b Plot of catalytic peak versus CySH concentration.
b Plot of catalytic peak versus iodate concentration.
b Inset the plot of catalytic peak versus CySH concentration, c the detailed magnified region.
It is observed that 0.5 wt% Pd on MgAl2O4 has exhibited maximum catalytic activity.
Initially, the catalytic peak currents icat increase with the amount of TFA added.
The maximum catalytic efficiency was reached at ATP concentrations between 0.5 2.5 m m (Table 1).
Maximum catalytic activity was found at 1 M NaCl with residual activity of 30% at 3 M NaCl.
When micellar substrates are used, maximum catalytic activity occurs at pH 7-8 and 30 55°C [ 17, 28, 34– 34]).
The amplitude was defined as the maximum peak-to-peak voltage of the MEP.
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