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Maximal adsorption of structurally similar azo dyes Orange G and Methyl Orange is < 10 μmol per gram of P25 titania [22], hence in our experimental setup the azo dye amount exceeds the titania adsorption capacity by about two orders of magnitude.
Secondly, conditions for maximal adsorption of bovine serum albumin (BSA) or a recombinant, heat-shock protein from Mycobacterium leprae (18 kDa-hsp) onto DODAB-covered or onto bare silica were determined.
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Offering the DODAB bilayer on silica to the protein improved BSA maximal adsorption for both intervening media.
The dry condition is considered as the situation of the maximal adsorption capacity of the shale gas reservoir.
The maximal adsorption capacity of SH-ePMO is lower than the capacities of mesoporous organosilicas reported in literature [12, 13].
According to that model, the maximal adsorption capacity of Gd-DTPA complex on magnetite/chitosan composite is 0.59 mmol/g.
At 40 °C, the modified powders displayed a maximal adsorption capacity of 0.23 mmol/g that is smaller than the initial unmodified material.
In the adsorption tests, the adsorption capacity was derived from the Langmuir isotherm model, and the maximal adsorption capacity of as-prepared adsorbents was 119.0 mg g−1 for Cu II) and 160.0 mg g−1 for Cd II).
Wherever possible, the Langmuir model was employed for isotherms linearization and determination of adsorption constants such as affinity constant (K, in M-1) and maximal adsorption (in number of molecules per m2 silica) [ 49].
In the region of maximal adsorption, i.e. capacitance pit in the differential capacitance versus electrode potential curve, the heterogeneous adsorption and diffusion steps are the rate determining stages for camphor and 2,2′-BP adsorption at the Bi(1 1 1) electrode.
While BSA appeared to be in a ordered end-on position occupying about 14 nm2 at maximal adsorption (Table 2) under conditions of moderate electrostatic attraction between BSA and silica/DODAB (1 mM NaCl, pH 6.3) further increasing this attraction drove massive BSA adsorption onto the particle as detected from the small area occupied per protein on the silica/DODAB surface, about 3 nm2 (Table 2).
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