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The slower dynamics is caused by an increase in entanglement density due to mixing/interactions between matrix chains and compatibilizer chains chemically attached to the droplets.
This "solid-phase nano-precipitation" does not occur under oxidative conditions, where the nanofiller preferentially undergoes crosslinking with matrix chains and is thereby immobilized.
These results suggest that entanglements between matrix chains and the non-adsorbing block impart good stress transfer and interfacial strength across the interface.
It depends on the completeness of the collapse of the chains that represent the filler particles, the mobility of these particles, their concentration, and the relationship between the number of beads in the matrix chains and filler particles.
The response of the mean square radius of gyration, 〈s2〉matrix, of the free matrix chains to disordered arrangements of the filler particles is evaluated for differences in the compactness and mobility of the filler particles, and for various relationships between the mass of matrix chains and filler particles.
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The formation of rigid amorphous fraction (RAF) layer around SiO2 with the thickness of 16.4 nm led to the adjacent molecular packing frustration, while the "lubrication" effect of nonwetting interface between the grafted crosslinked chains and matrix chains resulted in the segmental acceleration and the reduction of dynamic fragility.
This idea was first introduced by März [4], and it involves splitting the DAE system into differential and algebraic parts using projector and matrix chains.
The effective thermal conductivity of both thin film and bulk composites is found to sensitively depend on the interaction between tethered and matrix chains.
Since the filler particles and matrix chains are constructed from the same repeat unit, all of the intermolecular energetic interactions in the system (filler filler, filler matrix, matrix matrix) are identical.
The interface relaxation was characterized around 300 s in the GT5 nanocomposites, due to the entanglement between the long grafted and matrix chains, which also contributed lots to the rheology properties enhancement, such as the improving viscosity.
Setting E 0 : = E, A 0 : = A, then the projector and matrix chains of the matrix pair ( E, A ) can be written as: E j + 1 = E j − A j Q j, A j + 1 : = A j P j, j ≥ 0, where the image space of the projector Q j is equal to the nullspace of singular matrix E j, i.e., Im Q j = Ker E j and P j = I − Q j is the complementary projector.
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