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Though the Freundlich equation adequately described the sorption data, we attribute this sorption behavior to reduction in micropore overlapping effects and an increase in mass transfer caused by higher concentration gradients.
The low activity was possibly due to the activity loss during the immobilization process and/or the hindered mass transfer caused by the ZIF-8 framework, which was commonly observed in most cases of immobilized enzymes (Kim et al. 2008; Brady and Jordaan 2009; Hanefeld et al. 2009).
This may be due to limiting mass transfer, caused by the feed solution being almost four times more dilute than other experiments using the same membrane (normalized in terms of eq/L; Prakash and Sengupta, 2003), or the higher stability of divalent organic complexes over trivalent (Elliott et al., 1990).
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The reactions were found to be controlled by mass transfer limitations caused by coke deposition.
The enhancement factor R of the physical mass transfer coefficient caused by cellular convection is suitably described by the relation R = (Ra/Racr)u.
The proposed model can be used to simulate and systematically analyze mass transfer enhancement caused by the flow induced by a pair of electrodes.
A linear stability analysis is applied to a liquid-liquid system in which mass transfer is caused by a reversible interfacial reaction of pseudo-first order of the type present in some metal extraction processes.
Although physical qualities such as mesoporosity have been recognized as important, no significant attention has been paid to the influence of mass transfer barriers caused by various manufacturing processes and those induced by certain contaminants on the performance of FCC catalysts.
This is in accordance with the recent findings of Hodge and co-workers who concluded that possible mass transfer limitations caused by insoluble solids were not apparent at below 20% insoluble solids content [ 25].
Fungal cell pelletization has been widely researched because of its several advantages, such as increasing performance on the mixing and mass transfer properties caused by viscosity, decrease of the fermentation broth, easier separation and so forth [ 17, 19, 35].
The genome of C. psychrerythraea 34H was noted to possess a large number of extracellular enzyme coding genes (Methé et al. 2005), and dwelling at extreme cold seems to require the production of large amounts of extracellular enzymes to overcome the mass transfer limitations caused by low-temperature impairment of enzyme function and transport (Struvay and Feller 2012).
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