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However, CT removal could also be fit by a first-order mass transfer analytical model, potentially leading to an erroneous conclusion that the long-term tailing in the experiment was kinetically controlled due to rate-limited NAPL evaporation.
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It is shown that studying the absorption of CO2 into aqueous solutions of sterically hindered amines requires a rigorous numerical solution of the differential equations describing the mass transfer instead of analytical and numerical approximations based on a reduction of the number of reactions by neglecting or lumping reactions.
Mass transfer computations using the embedded analytical description approach show good agreement with the experimental results and the correlations.
The mass transfer rate coefficients and the analytical solutions are applied to simulate transport of an example volatile organic compound in an aggregated soil.
An analytical method to determine mass transfer coefficients from the experimental data is developed.
Numerical and analytical solutions are developed to characterize the mass transfer at Biot numbers Bi<10.
Mass transfer coefficient (m/s).
mass transfer coefficient.
Overall mass transfer coefficient (s−1).
mass transfer coefficient (L m−2 h−1).
External mass transfer coefficient (m/s).
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