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The same mass of analyte was injected in both cases [39].
where CSBSE and CW are the analyte concentration in the SBSE and the water phase, respectively, mSBSE and mW are the mass of analyte in the SBSE and the water phase, respectively and VSBSE and VW are the volume of PDMS and water phase, respectively.
Table 2 Recovery values in percentage for the selected estrogens using the SPE BetaBasic column in HPLC water samples Estrogens Recovery E3-3S 117 E3-17G 98 E2 96 E1 941-3S 88 EE23S 103 E3 95 E2 96 E1 94 EE2 72 Recovery values were calculated comparing off-line small injection method (25 μL) with online 1 mL injections (same mass of analyte injected) (C = 500 ng L−1, n = 5).
Unlike the SPR signal, the impedance response is not scaled with the mass of analyte molecule and is insensitive to nonspecific bindings caused by electrostatic interactions.
For the 1 2 ratio calculation, the molecular mass of analyte FLAG BRI1 was taken as 88 kDa corresponding to the putative dimeric protein.
The second major problem connected with the use of LA-ICP-MS for direct analysis of solid samples is the difference in the interaction between the laser beam and the sample surface observed for various matrices, causing changes in the mass of analyte ablated per pulse due to differences in the properties of the matrices investigated (e.g., absorptivity, reflectivity, and thermal conductivity).
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One is high-resolution mass spectrometers, which calculate elemental composition and nominal mass, because they can determine the exact mass of analytes; they are tools to identify unknown substances in the samples.
The mass of analytes bound onto the HR-MBG increased linearly for the first 60 min after which the binding rate decreased as the solution approached total depletion.
With this type of injection, multiple injections are made into a liner while the solvent is vented off, trapping the analytes and increasing the mass of analytes present in the liner.
The standard mass was averaged across ten scans providing a continuous reference for mass correction of analyte data.
The standard mass was averaged across 10 scans providing a continuous reference for mass correction of analyte data.
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