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Entropy generation minimization for a class of isothermal crystallization processes with a generalized mass diffusion law is investigated in this paper.
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For the given total mass of crystals, the optimality condition corresponding to the MEG (Minimum Entropy Generation) of the process is obtained firstly, and special cases for both the linear [g∝Δ] and the diffusive [g∝Δ(c)] mass diffusion laws are further derived.
This behaviour is explained with Fick's diffusion law where the concentration gradient as the driving force for the mass transfer rate, hence higher C i resulted in higher q e (Frijlink et al. 2015).
This behaviour is attributed to the Fick's diffusion law which stated that the concentration gradient provides driving force for the mass transfer rate, hence higher C i resulted in higher q e (Frijlink et al. 2015).
D mass diffusion.
Mass diffusion coefficient (cm2/s).
Physical effects of mass diffusion, heat conduction, mechanical motion, polarization and polarization relaxation in the mixture of the multi-component system, including their coupling effects, are formulated in accordance with the basic laws in non-equilibrium thermodynamics and continuum electrodynamics.
Binary mass diffusion coefficient of species i (m2/s).
Mass diffusion coefficient of species in the mixture m (cm2/s).
The effect of different power law exponent on the quality factor of the micro-beam is studied and Comparisons are made within the theory in the presence and absence of the mass diffusion effect.
If the chloride diffusion coefficient is constant, Equation 1 is usually referred as Fick's first diffusion law.
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