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The exothermic irreversible reactions A + B → C (main reaction) and C + B → D (side reaction) occur in the CSTR.
Fouling of an adiabatic fixed bed reactor has been simulated for a process where both the main reaction and the fouling reaction occur by a Langmuir-Hi mechanism.
This relationship is used in the design together with the kinetic models of the main reaction and of the deactivation by coke, in which the effect of attenuation by water in the reaction medium is taken into account.
Runs with high ratios of hydrogen to pentane did not show any deactivation and served to determine the kinetics of the main reaction and the principal side reaction, hydrocracking.
Measurements were made in the main reaction and post-reaction zones for a number of low molecular weight species, aliphatics, aromatics, and polycyclic aromatic hydrocarbons (PAHs) ranging from two to five-fused aromatic rings.
The kinetic model is a separable one, with a kinetic equation of the Langmuir Hinshelwood Hougen Watson type for each one of the steps of the main reaction and of the deactivation reaction.
Similar(49)
Systematic thermogravimetric analyses of urea and its most important by-products, such as biuret and cyanuric acid, are performed to gain the main reactions and their rates.
A 6-step kinetic model was designed that addresses the main reactions and hydrophobic interactions involved in this template-directed, autocatalytic system and that gave rise to excellent fitting of 4 previously published independent experimental series.
A novel parameter, γ, associated with anode materials was proposed to quantitatively describe the effective current applied to main reactions and its value could be achieved through EIS fitted data of the components in equivalent electrical circuits (EEC).
A set of differential equations were established considering kinetic expressions for the main reactions and mass balances for ferritin, iron and a discrete population of ferritin species defined by their respective iron content.
In the presence of these immobilized complexes, 1-hexene, CO and methanol give methyl-heptanoate and 1,1-dimethoxy-heptane as the main reaction products and minor amounts of heptanal.
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