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In spite of relatively high selectivity towards propylene oxide (reaching up to 23%), the main oxidation product was still propionaldehyde.
This product was found also as the main oxidation product in the presence of oxygen.
The main oxidation product was hydroxyacetone (HA) while minor oxidation products were acetaldehyde and acetic acid.
For pHs lower than 10, the main oxidation product is nitrate instead of N2, as reported previously.
Cr2O3 was the main oxidation product on the surface of the coatings along with a small amount of NiO and NiCr2O4.
In a series of experiments in which different concentrations of C2H4 were added to the feed, it was found that the main oxidation product of ethylene was CO2.
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Acetic acid, formic acid and carbon dioxide were determined as the main oxidation products of acetaldehyde.
The reaction pathway was also investigated: cyanate, nitrite, nitrate and carbonate were found to be the main oxidation products.
Primary and secondary alcohols were confirmed to be the main oxidation products of this material, and the total percent oxidation correlated with data obtained from oxidation rate measurements.
In order to elucidate the reaction mechanism of the process, the main oxidation products after a preparative electrolysis were detected by HPLC-MS.
On the other hand, Cr2O3 along with a small amount of NiO were the main oxidation products on the surface of the NiCr and NiCrMo coatings, and were found to be relatively less protective.
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