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The membranes were prepared by crosslinking hydrophilic poly(N,N-dimethyl acrylamide) (PDMAAm) main chains with hydrophobic di-, tri-, and octa-methacrylate telechelic polyisobutylene (PIB) stars.
In addition, the thermal decomposition temperature of Nafion® backbones shifted to higher temperature region due to the strong interaction of polymer main chains with organo-clays.
To overcome it, a new PESU was synthesized by replacing one diphenyl sulfone unit in the main chains with a bulky and rigid 1,2,4-trimethylbenzene moiety so that the new PESU (referred to as poly trimethyl phenylene ethersulfone (TPESU)) has a greater permeability and less aging behavior.
One was layer structure which formed from aggregations of main chains with d-spacing of 15.7 Å (2θ=5.64°) or from side chains with d-spacing of 36.6 Å (2θ=2.41°); The other was crystallosolvate region formed within aggregation of main chains (2θ=10 35°), and the kinetics of isothermal crystallosolvate was analyzed by means of the Avirami equation.
The results suggest that efficient degradation of wheat arabinoxylan is achieved by the first cleavage of the main chains with XynBE18 followed by branch removal with Ac-Abf51A.
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The side-chain mesogens are packed around the main chain with their axes almost perpendicular to the main chain.
Polymers with phosphorus in the main chain with intrinsic disordered framework for lithium-ion conductivity were synthesized.
This investigation relates to the synthesis and characterization of four linear polyelectrolytes containing crystal violet and bipyridinium moieties in the main chain, with molecular weights ranging from 1154 to 3815.
This result indicates that reducing stiffness of main chain with flexible junctions and also optical anisotropy are effective in decreasing CR.
Persistence lengths of the samples exhibiting comb-like topology were larger compared to linear polystyrene backbone and P tBuMA) side chains in THF suggesting stiffening of the main chain with increasing size of the attached side chains.
Molecular dynamics (MD) simulations of several polyethylene copolymer chains containing 1,2-, 1,3- or 1,4-disubstituted cyclopentane or hexamethylene structures in the main chain (with 500 CH2) are performed to investigate the influence of cyclic units on the crystallization properties of polyethylene (PE).
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