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The rearrangement reaction of the main chain, the cleavage reactions of ether and methylene bridge between benzene rings, and the elimination of a methyl group from a side chain were selected.
For the nanowires whose length direction is along the main chain, the probability of the short nanowires to meet the ends of other molecules to grow longer is very small.
With increasing flexibility of the main chain, the dynamics of the backbone becomes faster for the non-substituted polymers while an opposite trend is observed in the oxydecylperfluorodecyl substituted side-chain materials.
The original polymer matrix PhC-2 is the linear heterocyclic copolymer containing in its macromolecule's main chain the –HNCO– amide group linked at both sides by phenile fragments.
Given the absence of permanent dipole moment along the main chain, the α′ cannot be related to the so-called normal mode.
Thus, it can be explained by a rotational distortion around the main chain, the presence of the charge introducing strong electrostatic interactions which could hinder the packing of the chain following the usual hydrogen bonding pattern.
Similar(53)
The peripheral ethylene of the hexyl chain undergoes additional van der Waals interactions with the main chain of the inner helix residues G99, the side chain of I100 from a neighboring subunit, and the main chain of T74.
The base of nucleotide 1 abuts the surface formed by the main chain of the protein (residues 366 368) and interacts with it through van der Waals contacts.
The main chain of the substrate at P3 interacts extensively with the enzyme, although the side chain has some flexibility.
The monomers of the main chain and the side ones are assumed to be flexible with a statistical length a.
However, Ala62 completely lost the interaction with TP5 by its side chain oxygen which was replaced by the main-chain oxygen of Ala62 (Fig. 7C, D), suggesting that the interaction by the main chain weakened the binding affinity.
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