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Novel chiral polymers containing cinchona-based squaramides in their main chain structure were designed.
Poly (glycidol) has a main chain structure similar to that of poly (ethylene glycol) (PEG), which is a well-known fusogenic polymer.
Accordingly, a control of molecular weight of polymer and main chain structure is possible in the polymerization of VC with tert-BuLi.
Because of having the same main chain structure, it was observed that PECH and PGA networks acquired the same solubility parameter value.
Structure analysis of the resulting polymers indicates that the main chain structure could be regulated in the polymerization of VC with tert-BuLi.
The reason is that the alteration of the main chain structure leads to the increase of the highest occupied molecular orbital (HOMO) level of the polymeric host, which can facilitate the efficient hole injection and transportation.
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The copolymers exhibit different glass transition temperatures (Tg), from 46 to 143 °C, due to their different main chain structures.
This result suggested that PAr1 had a highly flexible main-chain structure.
Here, we present and apply a statistically based, computational approach for identifying the properties of sequences compatible with a given main-chain structure.
Calculations are performed for a variety of similar backbone structures to identify sequence properties that are robust with respect to minor changes in main-chain structure.
The high temperature performance and low-dielectric constant could be attributed to the polycarbosilane main-chain structure and the benzocyclobutene-based cross-linked structure.
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