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Main chain LCPs included a random copolyester (Vectra® A950) and an azomethine alternating copolymer.
The new model was evaluated by studying the phase behaviors of semi-flexible main chain LCPs through simulation.
The molecular chains of LCPs are depicted by a newly developed molecular model named GB-spring-bead model, which has proved to be efficient and accurate in studying the phase transition behaviors of semi-flexible main chain LCPs [Yung KL, He L, Xu Y, Shen YW. Polymer 2005 46:11881 [1]].
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In this study, a commercial grade diepoxy reagent (Heloxy 67) was used to modify the rheological properties of a thermotropic main chain LCP.
Four species of molecular architectures were studied, a rigid main-chain LCP, two types of flexible main chain LCP, one with mesogens oriented perpendicular to the backbone, the other with mesogens parallel to the backbone, and a flexible side-chain LCP with mesogens attached side-on to the backbone.
Wholly aromatic thermotropic main chain liquid crystalline copolymers (LCPs) with varying glass transitions (Tg) were tested for wear resistance, particularly under high friction conditions, where surface temperatures can rise.
This work investigates the miscibility of two commercially important thermotropic main chain liquid crystalline polymers (LCPs), Vectra A950 and Vectra B950, using dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC) and positron annihilation lifetime spectroscopy (PALS).
Linear LCPs can have flexible main chain, flexible side chain or rod-like main chain architectures.
Three copolyester LCPs which all contain a substantial fraction of main chain 1,4-phenyl groups were chosen for this study.
Main chain atoms only are shown.
The side-chain mesogens are packed around the main chain with their axes almost perpendicular to the main chain.
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