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This pattern was indicative of an edge-on orientation, in which the P3HT main backbones and the hexyl side chains were parallel with and perpendicular to the substrate, respectively.
The dimensions of these single crystals in the a [thickness of single crystal or hexyl side chains or (100) direction], b [length of single crystal or π π stacking or (020) direction], and c (width of single crystal or longitude of P3HT main backbones) axes were 437.50 nm, 64.55 µm, and 116.87 nm, respectively.
In the SAED patterns of Fig. 1b, two pairs of (100) prisms in the a-axis or the hexyl side chains direction and two pairs of (020) prisms in the b-axis or the π π stacking direction demonstrated a flat-on orientation for the P3HT chains, in which the main backbones and the hexyl side chains were perpendicular and parallel to the substrate, respectively.
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