Sentence examples for macroscopic rate from inspiring English sources
The multi-scale structure model includes: (1) micro/meso/macro-structure model with periodic boundary conditions for homogenizing the heterogeneous fiber/resin system into unit cells, and (2) a macroscopic rate dependent plasticity model combined with critical damage area failure theory that accounts for the compressive deformation and failure strength of the composite material.
Our results indicate that even in the presence of slow conformational fluctuations macroscopic rate laws will hold in this limit.
In this paper we investigate the applicability of macroscopic rate laws for fluctuating enzyme systems in which catalytic transitions are slower than ligand binding-dissociation reactions.
Despite these fluctuations, there exist some limiting cases in which the enzymatic catalytic rate follows the macroscopic rate equation such as the Michaelis-Menten law.
The goal of this work is to investigate the general applicability of macroscopic rate laws for fluctuating enzyme systems in the quasi-equilibrium limit.
Slow conformational fluctuations which are a source of dynamic disorder are common to many enzymes and can lead to deviations from macroscopic rate laws as predicted by conventional chemical kinetics.
A novel macroscopic rate-equation propagation model is used which considers concentration-dependent rates for the energy-transfer inter-atomic migration-assisted mechanisms.
In this letter, we rely on MD computer simulations to roundly probe how spatiotemporal distribution of shear-banding events on an atomic scale is related in situ to macroscopic rate-dependent serrated plastic flows in BMGs undergoing nanoindentation.
However, macroscopic rates, such as V influx and V efflux, follow the Michaelis Menten kinetics.
The macroscopic rates have either been fit with a complex functional dependence on ΔGr [2 5] or fit with inferred dissolution mechanisms; such as the ion exchange model [18] or pit nucleation model [6, 7].
With this spectroscopic membrane permeation cell, it is possible to correlate microscopic surface processes to macroscopic rates of permeation across the membrane, which will enable the rational design of new membrane materials that are resistant to deactivation.
