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The absence of flower-like micelles in dilute solutions and the macroscopic phase seperation suggest that the gels in the pentablock are formed by random association of multiplet domains and not by bridging of micellar domains.
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A proper formulation of an emulsion should be stable against droplet coalescence and macroscopic phase separation.
We differentiate between molecular solubility, mesoscale solubilization, and macroscopic phase separation.
Phase separation temperatures were measured turbidimetrically and by determining the first discernible macroscopic phase separation.
For the semi-IPNs, however, Na+-MMT induced macroscopic phase separation and resulted in lower mechanical properties.
However, the macroscopic phase separation occurred in the thermosetting blends of epoxy resin with s-PMMA-b-PS block copolymer.
Depending on chemistry and architecture, they can create percolating clusters and transient gels or they can show macroscopic phase separation into a dilute and a structured dense phase.
No macroscopic phase separation was observed for this system, and the mixed solutions were almost transparent in the whole DN range examined.
A macroscopic phase separation was observed for the systems of C copolymer = 50 and 100 g/L, and the solution became opalescent at DN = 1.0, indicating precipitation.
Too large solvophobic domains can lead to macroscopic phase separation.
This polymer exhibits a lower critical solution temperature (LCST) around 32 °C [ 22] with a heat-induced macroscopic phase separation.
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