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By replacing NaPSS by a statistical copolymer with maleic acid, the region of macroscopic phase separation becomes smaller and macroscopically homogeneous one phase systems are now formed over a much wider range of the phase diagram.
The PVP PSS blends were macroscopically homogeneous, although the blends of PVP with polystyrene (PS) showed macroscopic phase separation.
A proper formulation of an emulsion should be stable against droplet coalescence and macroscopic phase separation.
We differentiate between molecular solubility, mesoscale solubilization, and macroscopic phase separation.
Phase separation temperatures were measured turbidimetrically and by determining the first discernible macroscopic phase separation.
For the semi-IPNs, however, Na+-MMT induced macroscopic phase separation and resulted in lower mechanical properties.
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H4 with 10% PDMS-OH as a typical macroporous and the homogeneous material, in which the macroscopic silica phase separation was prevented as in-situ sol gel process, provided improved surface adhesion properties.
(A ) In the absence of actin, our Mica supported model membrane revealed a phase transition at T c ≈ 28°C, below which macroscopic Lo/Ld phase separation was observed.
Our data indicate that amyloid oligomer formation shares intriguing similarities and display important differences with both macroscopic liquid liquid phase separation in proteins as well as with surfactant self-assembly.
However, in a previous case[ 26, 37] of ILs with fluorinated anion alkyl cation assemblies macroscopic homogeneity was achieved simply by naturally maintained charge neutrality, whereas in the case of the present mixtures, phase separation on the macroscopic scale can be induced by the very same fluorophobicity that may result in the interesting microscopic triphilic structure.
However, thermoplastics/thermosets blends are problematic because such blends naturally tend to phase separation on the macroscopic scale.
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