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It has been previously been thought that PEG incorporation increases the relaxivities of liposomal MRI contrast agents, due to additional macromolecular bulk structure, causing reduced tumbling rates and hence increased Gd-metal water contact [16,27].
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Although the membrane composition of the models in this and our previous study differ, it was theorized that the bulk macromolecular structure would be substantially the same.
Further, WCA increases with the increasing aging time, which can be explained by the rearrangement of the newly created functional polar groups of the macromolecular chains into the polymer bulk [19].
Comparing of the WAXS diffractograms of the cationic and anionic polyelectrolytes on whose basis the IPEC was formed (see Fig. 1), it was found that P4VP has only short-range ordering while translated in bulk a fragments of the main macromolecular chains and their lateral branches pyridine ring (curve 1), and pectin has an amorphous crystalline structure (curve 4).
Nanomaterials may have complex macromolecular structures and often display increased reactivity compared with their bulk counterparts.
Gel permeation chromatography-light scattering and bulk intrinsic viscosity measurements were used for the macromolecular characterization.
Nearly all models of water relaxation in macromolecular systems consider one or more new groups of protein-associated water with altered motion that contributes to bulk water relaxation.
Its bulk,.
Bulk matters.
Bulk bad.
Protective Trend Bulk.
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