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This could be attributed to the macro phase separation of gels with matrix at relatively higher loading.
This reaction turned out to promote POSS well dispersed in the polymer matrix, and the PSMA-POSS hybrids showed no macro phase separation even if POSS concentration was up to 30 wt%.
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However, macro phase-separation, giving a co-continuous microstructure, accompanied by local phase-inversion, dominates the RIPS blends containing more than 8 wt% sPS.
Divided by a Lifshitz line, bulk polyelectrolyte solution undergoes either micro- or macro-phase separation.
Deviations from this linear trend are shown to result from the macro-phase separation induced by the poor compatibility of SBS and bitumen.
In a similar manner, when PS-b-P4VP/P4VP block copolymer/homopolymer solutions were spincoated, the P4VP homopolymer was solubilized in the P4VP block domains during spincoating, suppressing macro-phase separation.
An aromatic amine, an acid anhydride and an anionic polymerization catalyst as curing agents resulted in macro-phase separation in the epoxy/triblock copolymer blends during the cure process.
During the selective solvent titration, the solution underwent a macro-phase separation that was mainly related to PAA, followed by a micro-phase separation that corresponded to the formation of vesicles with the shell of PB block and the core of PAA/PEO complex.
The reported method combines macro-scale temperature induced phase separation and micro-phase separation of block copolymers to produce highly porous scaffolds with surfaces comprised of nano-scale self-assembled block copolymer domains, representing a significant advance in currently available scaffold engineering technologies.
SEM micrographs did not show any phase separation in the macro-scale.
Organosilicate scaffolds were synthesized through a technique combining surfactant-templating and phase separation to produce a macro-textured scaffold with a combination of micro- and mesopores.
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