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For the alkylation reaction, the SZ catalyst gave a higher C5+ alkane yield and much lower selectivity for trimethylpentanes (TMPs) at 2 h TOS.
Low acidity ZSM-5 was particularly chosen for its lower activity in respect to zeolite-acid catalyzed reactions (i.e. hydrocracking) which might lead to the lower selectivity for the light hydrocarbon and high selectivity for gasoline range components and for its high stability.
HCN channels are thought to be structurally similar to Kv channels, but show much lower selectivity for K+.
By contrast, HCN channels have a pore-lining sequence of LCIGYG (Figure 1A) and have a 20 fold lower selectivity for K+ over Na+ ions compared to K+ channels [11], [18], [19].
Along the same line, [F]-AII presented almost 4 times lower selectivity for AT2R in comparison to the [Y]-AII analogue.
In the case of HKUST-1, samples obtained after a longer synthesis time systematically display a lower selectivity for campholenic aldehyde while more products of Brønsted acid reactions are observed.
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The lower selectivities for P. aeruginosa stem from MICs that are 5 6× higher than those for E. coli and S. aureus.
Acidic or alkaline conditions enhanced the binding of both HIgG and HSA, but resulted in lower selectivities for the two proteins.
The reasons for the lower selectivity were not explored, and the correlation of P-gp expression with selective toxicity was not assessed.
These higher activities result in a lower optimal reaction temperature for the oxidative coupling of methane and are (at least partially) responsible for the lower selectivity to C2 products observed with the Ca/Sm2O3 catalyst compared to that with the Li/MgO catalyst.
Crown ether 3 showed enhanced extractability for all cations but lower selectivity compared to 18-crown-6.
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