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The direct signal analysis was applied to the low temperature spectrum in order to decompose the complex band in elementary curves characterized by Arrhenius relaxation times.
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Analysis of low temperature spectra made it possible to determine energies of crystal field components of Sm3+ multiplets involved in the excitation and luminescence phenomena.
As for the RP case, the low temperature spectra can be analyzed by using two fitting components, corresponding to CO in on-top and bridge sites.
The dynamic range was sufficient for temperature measurements ranging from 300 K to 2200 K, although some detector saturation was observed for low temperature spectra.
Low temperature spectra showed the characteristics of rigid limit spectra, and in the range of 293 373 K, complex spectra were obtained with the slow component mostly arising out of the PMMA rich regions and fast component from the PI phase.
In the absence of substrate (top spectra), the lowest temperature spectrum exhibits the characteristic rhombic powder pattern of a six-coordinated nitrosyl complex.
The remaining 10% of total iron in the NO-reacted sample was a magnetically isolated S = /2 {FeNO} species (δ ∼ 0.65 mm/s, and Δ EQ ∼ −1.9 mm/s), which was observed in the low-temperature spectrum.
From the above discussion about low-temperature spectra of doped CdSeS NCs, we also can see the difference between the yellow-emitting and red-emitting NCs.
This small distance contraction was also noted for room- and low-temperature spectra of strontium sorbed to kaolinite [26] and probably results from a small anharmonic effect [25].
Low-temperature spectra were recorded in a backscattering geometry on samples maintained at ∼105 K in a liquid nitrogen coldfinger.
Segments of the low-temperature spectra are shown in Figure 3, stacked in proportion to the temperatures at which they were collected.
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