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The spherical YS type is superior in low specific area which can conduce to reducing surface tension.
In many reports hydrocarbon/H2 mixtures are employed but these reagents may give rise to low specific area materials at low flow rates.
Conversely, the nanofibers are characterized by a very low specific area, while the ceria obtained with SCS lies somewhere in between the other two morphologies.
The low activity of Csx Cuy/ZrO2 with high amount of Cs is explained by the low specific area and to the presence of CuO crystallites.
On the contrary, higher yields to HCHO (1.7%) and CH3OH (1.6%) can be achieved at 923 K over a low specific area catalyst.
In spite of their low specific area, the catalysts develop a good activity (up to 17% of H2S conversion for surface area lower than 1 m2 g−1) and an excellent sulphur selectivity (always higher than 95%).
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This proves that specific surface area is not the only important factor in solid-solid catalysis and that tailored morphologies can be achieved even with low specific areas.
For high specific surface area carbons (> 1000 m2 g−1), the IN is a relative indicator of BET surface area measurements, whilst for low specific surface area IN will devolve away.
Derived carbon particles exhibited high specific surface area with low structural ordering (active carbons) to low specific surface area with high graphitic ordering as a function of increasing reaction temperature.
They concluded that the carriers with a low specific surface area could be more effective in dissolution rate improvement as compared to the carriers of a high specific surface area (9).
This makes rocks with a large grain size to have a low specific surface area.
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