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The kinetic model suggests that the HOR/HER on metallic Ni follows the Heyrovsky-Volmer mechanism characterized by strong adsorption of the hydrogen intermediate and low reaction rate.
However, in the case of a highly endothermic reaction with an extremely low reaction rate and/or small chemical equilibrium constant, internal mass integration has also to be considered between the reactive section and stripping section.
Results indicate that active spreading for contaminants with low reaction rate coefficients should be conducted by using greater amounts of treatment chemical mass and longer injection durations relative to contaminants with high reaction rate coefficients.
The low reaction rate contributed to a thickened flame structure near the hot core, which reduced the heat transfer to the flame front and prevented effective evaporation and preheating of the fluid ahead of the flame front.
Usually, this kind of situation in two-phase approach, because of a small interface, generally causes low reaction rate.
On the other hand, a low reaction rate requires a longer reaction time (shut-in time) to form detectable concentrations of the product tracer.
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Carbon monoxide electrolysis has previously been reported to yield enhanced multi-carbon (C2+) Faradaic efficiencies of up to ~55%, but only at low reaction rates.
The low reaction rates allowed us to systematically study the formed particles.
Despite the great number of −CH2OH groups present in the compounds studied low reaction rates were found.
Conventional FTS processes like gas phase (fixed bed reactor) and liquid phase FTS (slurry reactor) suffer from low reaction rates and a wide range of products.
Transport limitations often occur in liquid/liquid systems and, for instance, are responsible for low reaction rates in homogeneous catalysed liquid/liquid reactions with water soluble catalysts.
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