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This study shows that it is possibile to change in a controlled way the catalytic properties by changing the density of low coordinated atoms on nanostructured surfaces.
Current density was found to increase significantly for smaller NPs due to the increasing population of strongly binding low coordinated sites on NPs below 5 nm.
Since silver preferentially populates edge, corner and other defect-like sites, the weakly bound β was correlated with low coordinated metal atoms.
Both low coordinated lattice Si and Al atoms were detected and differences in the mechanisms of the dehydroxylation of zeolites prepared by direct chemical synthesis and by deep dealumination were studied.
Reactors work at high temperature and pressure, while the catalysts consist usually of supported powders exhibiting different atomic terminations and a high concentration of low coordinated sites (steps, kinks, vacancies etc).
The O 1s spectra of the sample was also presented in the inset of the same figure The peak at around 530 eV is due to lattice O, while the peak at about 531.6 eV can be attributed to the low coordinated oxygen ions (chemisorbed oxygen) at the surface [25].
In this sense, the addition of cerium by ion-exchange with [Ce(EDTA)]− complexes resulted in higher activity and selectivity, due to an increase in the reducibility of nickel species and to the introduction of new intermediate and strong basic sites (acid-base pairs and low coordinated oxygen species).
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The stabilization of photogenerated holes as O− radicals by low coordinate bridging O2−, more marked for P6H than for P11T, is favored by weakly adsorbed water.
A different approach for the formation of imines was based on gold(I -phosphine complexes bearI -phosphineordinating bis(trifluoromethanesulfonyl) imidate complexesn, namely SPhosAuNTf2.
Several point clusters with low S coordinate correspond to inland seas (Caspian, Black, Baltic) and the Arctic.
kern-0pt} {partial Q}} < 0), it follows that the supplier's production quantity is too low to coordinate the supply chain.
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