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At the low conversion conditions chosen only oligomerization reactions occurred.
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The temperature measurement along the axial position and image observation of the catalyst packed-bed indicated that the flame was stably held at the interface of the PM and the catalyst bed, and this enhanced fuel conversion and reforming efficiencies, especially in the low methane conversion condition.
The proposed improvements from this study have been validated for both low solids conditions and at endpoint conversion conditions for high solids.
However, subjecting only imine 9 as starting material to the reaction conditions resulted in only a very low conversion (see the Supporting Information for more details).
Catalytic activity tests with the bare supports under the similar conditions used in this study resulted in very low conversion (<10 %), also the initial rates of conversion of glycerol and formation of propanediol have a proportional increase with the catalyst amount.
However in our conversion conditions PrP is in the state of lowest free energy if it is refolded for attachment to the fibrillar seed.
The backward reaction (reverse WGSR) was neglected owing to the low conversion and the large distance from the equilibrium under the applied reaction conditions.
Ni/CaO/Al2O3 catalyst exhibits the highest methanation activity with CO conversion higher than 93% and a relatively low conversion of CO2 into methane among investigated catalysts at 300 °C under the operating condition.
However, all catalysts, included NiMo/Al2O3, suffered a rapid deactivation under the reactions conditions used, which was attributed to a desulfurization of the catalysts caused by the low conversion level obtained and, therefore, a low H2S partial pressure in the reactor.
Accordingly, we observe dynamic inhibition at low temperatures and in hydrothermally aged states, but predict its existence very near the catalyst front in higher conversion conditions where we did not specifically monitor its impact.
A low conversion ratio?
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