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Concentrations below the LOQ were treated as one-half of the respective LOQ in the calculations [ 24].
Bromoform concentrations were below the LOQ in all samples.
Similarly, LOQ in the above equation is defined as 10σblank.
As and Cd concentrations were lower that the LoQ in all the analysed samples.
The excellent electroanalysis of hydrogen peroxide with the limit of detection (LoD) and limit of quantification (LoQ) in the μM range was obtained.
Open image in new window Fig. 8 Seasonal CH/THMs ratio for Plant 1 and Plant 2. For HANs, TCAN and DBAN were below LOQ in all samples in Plant 1 and Plant 2. DCAN was found in 75 and 67%% from samples of Plant 1 and Plant 2, respectively.
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LOQs in 0.04 0.2 μg/g range were calculated, making feasible the determination of these compounds of nutritional concern at trace levels.
PFOA, PFNA, PFDA, PFUnA, PFHxS, and PFHpS were detectable at significantly lower levels, while PFBA, PFHxA, PFBS, and PFDS concentrations were below the respective LOQs in most samples.
Under the optimum conditions (extraction time 40 min, stirring rate 650 rpm and salt content 0.3% NaCl w/v) the validated method presented a high sensitivity and selectivity with LODs and LOQs in the range of 10.1 13.6 and 33.3 43.9 ng/L, respectively.
The Sf-Loq dsRBM is highly analogous with Bm-loq in comparison to Tribolium or Drosophila homologs.
The concentrations of the six PCB congeners, p,p´-DDE, and HCB were above the LOQs in all samples.
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