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The influence of different linking positions of carbazole-oxadiazole substituents on the thermal, photophysical, electrochemical and charge transport properties of the compounds is comprehensively studied.
A new class of bipolar compounds were designed and synthesized based on 9,9-dimethyl-9,10-dihydroacridine and phenylphenanthroimadazole/triphenylimadazole derivatives with different linking positions.
Four covalent BODIPY hetero-dimers, formed by different linking positions at (2,2′), (2,8′), (3,8′) and (8,8′) respectively, were designed and synthesized to compare their ability for excited triplet state (T1) and singlet oxygen generation.
In particular, the redox and optical properties appear to be strongly dependent on the linking positions within the polymer, imposed by the ligand design, and able to be tuned through strategies such as copolymerisation.
In this paper, a series of new bipolar blue host materials has been designed and synthesized by incorporating dimethyl or diphenyl silane core with connection of carbazole di biphenyl) groups at different linking positions.
The highly nonlinear calibration plot can be explained by the variety of the linking positions to the protein, each having different oxygen accessibility.
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We demonstrate that the fluorescence properties of these complexes are highly affected by the linking position of the anthracene unit, as only 2 shows fluorescence emission in the blue region.
These results prove the simple modification of adjusting the linking position of electron-deficient substituent groups in the molecules can effectively fine-tune the emissions of TADF emitters but without significantly changing other key performance.
This is due to its linking position between the copper binding histidine (His2543) and the nearby FU surface as well as its immediate neighbourhood composed of hydrophobic and hydrophilic amino acids.
The reduced selection pressure for the SIB_TRAIT results in smaller allele frequency changes of QTL affecting the SIB_TRAIT and of linked positions in the genome.
The reduced frequency changes/genetic drift at linked positions implies that the selection pressure for GROWTH results in more response for GROWTH.
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